화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 분자전자 부문위원회
제목 Simultaneous Enhancement of Efficiency and Air stability in Polymer Solar cell with modified PEDOT/PSS buffer layer
초록 In most of the bulk heterojunction (BHJ) OSCs, poly(4-styrene sulfonate)-doped poly(3,4-ethylenedioxythiophene (PEDOT:PSS) is widely used as hole transport layers (HTL). However, PEDOT:PSS accelerates the degradation of OSCs due to its highly hygroscopic and acidic nature. To solve this problem, PEDOT/PSS was modified to have a resistance from water using polymeric additive. As a results, power conversion efficiency(PCE) increased from 2.516% to 2.917% by 16% and half-life times also increased around 2 times. The electrical and morphological properties of modified PEDOT/PSS was analyzed by X-ray photoelectron spectroscopy(XPS), Kelvin probe, 4-point probe meter and atomic force microscopy(AFM) respectively. This method is very simple on the production process and shows a lot of applicability in various organic electric device such as OPV, OLED, OTFT etc..
저자 이정준, 이승환, 박홍관, 조원석, 이선종, 김중현
소속 연세대
키워드 Organic photovoltaic (OPV); PEDOT/PSS; Polymeric additive; Water resistance; Air stability
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