| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Preparation of PBT/Clay Nanocomposites using Supercritical Process. |
| 초록 |
Recently, polymer/clay nanocomposites have received considerable attention from both fundamental research and application point of view. This polymer/clay nanocomposite system could be followed by the in situ preparation of poly (butylene terephthalate) using a supercritical process. The ring-opening polymerization of butylene terephthalate cyclic oligomers was initiated by cyclic stannoxane 1 was carried out in supercritical chlorodifluoromethane(HCFC-22) at various pressure and temperature range. Chlorodifluoromethane was used as a solvent which has critical point (Tc=96.2℃, Pc=49.7bar). The nanocomposites are characterized by X-ray diffraction, transmisson electron microscopy, capillary viscometer, differential scanning calorimetry. |
| 저자 |
홍영기1, 윤호규2, 이윤우3, 이상수1, 박민1, 김준경1, 임순호1
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| 소속 |
1한국과학기술(연), 2고려대, 3서울대 |
| 키워드 |
supercritical; clay; nanocomposite; PBT
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| E-Mail |
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