화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 (한-태) 전자재료의 최근 동향
제목 Photocatalysis fundamentals and surface modification of magnetic core–shell Fe3O4/SiO2/CeO2
초록 Photocatalysis as a green and sustainable technology has received increasing attention during the past decades. Based on the fundamentals of photocatalysis and surface chemistry of CeO2 materials, we herein discuss a very facile and reproducible method for the synthesis of Fe3O4/SiO2/CeO2 with a control of core-shell structure. The first attempt in producing Fe3O4/CeO2 magnetic photocatalyst involved the direct deposition of CeO2 onto the surface of magnetic Fe3O4 particles. However a direct contact of CeO2 onto the surface of magnetic Fe3O4 particles presented unfavorable heterojunction, thus the SiO2 barrier layer between magnetic Fe3O4 and CeO2 was prepared as a core-shell structure to reduce the negative effect. Fe3O4/SiO2/CeO2 core-shell magnetic nanoparticles was recovered in the consecutive cycles of use by external magnetic field. The material showed good stability with regards to photocatalytic performance for three cycles of use.
저자 Duangdao Channei1, Sukon Phanichphant2, Auppatham Nakaruk1, Pramod Koshy3, Charles C. Sorrell3
소속 1Naresuan Univ., 2Chiang Mai Univ., 3UNSW Australia
키워드 CeO2; Photocatalyst; Core-shell structure; Magnetic photocatalyst
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