화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU))
권호 22권 2호
발표분야 석유화학.윤활유_포스터
제목 Iron-carbide catalysts derived from metal-organic frameworks (MOF) for CO hydrogenation
초록 Fischer-Tropsch Synthesis (FTS) reaction has been widely investigated to produce value-added hydrocarbons from syngas. Among a lot of active metals, iron-based FTS catalyst has been intensively investigated due to its lower cost, and high activities even at various operation conditions. In general, various iron carbide phases such as χ-Fe5C2 and θ-Fe3C can be formed which were reported as active phases for FTS reaction. These iron carbide phases can be synthesized using a simple pyrolysis method of metal-organic framework (MOF). By changing the pyrolysis conditions such as temperature or its duration time, iron carbide phases with various porosity and crystallite sizes can be synthesized, and the effects of these preparation factors were investigated in the present work.
저자 조재민, 배종욱
소속 성균관대
키워드 Fischer-Tropsch Synthesis; MOF; MIL-100(Fe); iron carbide; pyrolysis; condition; catalytic stability; product distributions
E-Mail