| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 가을 (10/28 ~ 10/29, 건국대학교) |
| 권호 |
9권 2호 |
| 발표분야 |
환경,에너지 |
| 제목 |
Production and Separation of Hydrogen from dimethyl ether using a membrane reactor |
| 초록 |
Dimethyl ether (DME) steam reforming was performed using a commercial Süd-Chemie Cu/Zn/Al2O3 catalyst in a fixed-bed continuous reactor and a Pd/Ni composite membrane reactor. The DME conversion of 77 % and the H2 composition of 50 % were obtained in the fixed-bed reactor while the membrane reactor provided almost 100 % DME conversion and 55 % H2 proportion at 420oC. Moreover, the H2 concentration of permeated gas through the membrane was 85 % which is higher than the theoretical ratio of H2 (75 %). Increasing the temperature from 360 to 440oC decreased the DME conversion from 70.3 to 99.9 % in the membrane reactor. The CO concentration of the generated gas decreased with increasing the molar ratio of H2O/DME. |
| 저자 |
이현주, 김선희, 남승은, 이규호
|
| 소속 |
한국화학(연) |
| 키워드 |
steam reforming; dimethyl ether; membrane reactor
|
| E-Mail |
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