| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_촉매 |
| 제목 |
Catalytic performance of MOF-801 catalyst for the cycloaddition of epoxides and CO2 |
| 초록 |
Carbon dioxide has been recognized to be a useful source for the synthesis of cyclic carbonate from CO2-epoxide fixation reaction through a eco-friendly route. In this study, MOF-801 has been synthesized using solvothermal method. The synthesized MOF-801 was characterized using various analytical techniques. The synthesized MOF-801 showed excellent catalytic activity for the synthesis of cyclic carbonate from epoxide and CO2. Reaction parameters were optimized by altering the reaction conditions. Recyclability of MOF-801 was tested up to five times without any considerable change in catalytic activity. Finally, a reaction mechanism for MOF-801 catalyzed cycloaddition reaction was proposed based on our previous DFT results. |
| 저자 |
구윤장1, Jintu Francis Kurisingul1, 우희철2, 박대원1
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| 소속 |
1부산대, 2부경대 |
| 키워드 |
Catalysis; MOF-801; CO2; Epoxide; Cyclic carbonate
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| E-Mail |
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