화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 봄 (05/01 ~ 05/03, ICC JEJU)
권호 17권 1호
발표분야 포스터-촉매
제목 Polymer-Supported Electron-Rich Oxime Palladacycles as an Efficient Catalyst for Microwave-Assisted C-C Coupling Reaction in Aqueous Condition
초록 Oxime palladacycles are highly active palladium catalysts for C-C coupling reactions, and possess advantages such as easy preparation, and air, moisture stability. In our previous work, electron-rich oxime palladacycle on polymer support was prepared to provide efficient C-C coupling activity and reusability of the catalyst for green purposes. For water-based Suzuki coupling reaction, we applied microwave chemistry to polymer-supported oxime palladacycle system. Suzuki reaction of aryl halide and heterocyclic halide with phenylboronic acid was successfully performed using polymer-supported electron-rich oxime palladacyles, utilizing the microwave system, to acquire reaction products in water medium.
저자 박성준1, 조홍준1, 이상명2, 이윤식1
소속 1서울대, 2강원대
키워드 Oxime palladacycle; Microwave
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