화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 가을 (10/27 ~ 10/28, 고려대학교)
권호 12권 2호, p.2578
발표분야 촉매 및 반응공학
제목 Photocatalytic docomposition of water-methanol solution over Pt/KNaNbTeO6 under visible light irradiation (λ>400 nm)
초록 Most of the applications have focused on TiO2, which shows high activity and long-term stability, and is inexpensive. However, TiO2 is active only under UV light due to its wide band-gap energy of ca. 3.2 eV. Since, the fraction of UV in solar spectrum is less than 5%, TiO2 photocatalysis cannot efficiently exploit the abundant natural resource i.e. solar radiation which dominantly consists of visible light. In order to utilize the main part of solar spectrum, and even for indoor applications under weak interior lighting, photocatalysts absorbing visible light are required. Here we describe single-phase oxide photocatalyst, KNaNbTeO6, cubic crystalline phase, which is an efficient photocatalyst for isopropyl alcohol degradation to CO2, and decomposition of water-methanol solution into H2 or O2, all under visible light.
저자 김현규1, 정의덕1, 김해진1, 홍태은1, 박혁규1, 지상민2, 배상원2, 홍석준2, 장점석2, 이재성2
소속 1한국기초과학지원(연), 2포항공과대
키워드 광촉매
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