| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
콜로이드·계면화학_포스터 |
| 제목 |
Cobalt-Cluster-based Racemic Supramolecules and Their Highly Ordered Polymeric Assembly Structure |
| 초록 |
We report the controllable synthesis of a highly ordered supramolecule-based polymeric structure, {[M,P-Co8(PDA)6(HIP)3(DMF)5(H2O)]3-[Co(DMF)(H2O)2]} (1) with unique zigzag-shaped topology. The solid-state structure of 1 reveals an alternate and periodical assembly of racemic monomeric species to form a polymeric platform. Discrete racemic supramolecular structure (2) which is analogous to the monomeric species of 1 is also controllably synthesized in a separate reaction. Intermolecular hydrogen bonds between hydroxyl group of HIPs and carboxylate oxygen atoms from PDAs of supramolecules are critical for the unique solid-state packing geometries of 1 and 2. |
| 저자 |
MAIDUYHIEN, 유효종
|
| 소속 |
한림대 |
| 키워드 |
Cobalt-based cluster; racemic supramolecule; higher-order assembly
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| E-Mail |
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