화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 분자전자 부문위원회 II
제목 Synthesis of Highly Twisted Pyrene Derivative for Pure Blue OLED
초록 We synthesized new fluorescent blue host material, BD4PP for pure-blue OLEDs. BD4PP has highly twisted and steric design for efficient fluorescence, and showes high thermal property of 492 oC. BD4PP host doped with 5 wt. % 4,40-bis(9-ethyl-3-carbazovinylene)-1,10-biphenyl (BCzVBi) or 5 wt. % 1,4-bis[2-(3-N ethylcarbazoryl)- vinyl]benzene (BCzVB) showed high device efficiencies based on wide bandgap (~3.1 eV) and electron-rich host. An OLED with the BD4PP:BCzVB emitter presented higher current and external quantum efficiencies (EQEs) of 4.41 cd/A and 3.80% with color coordinates (0.16, 0.13) compared to those of the BD4PP:BCzVBi (3.63 cd/A and 3.62%) with color coordinates (0.16, 0.11) and non-doped BD4PP (2.01 cd/A and 1.61%) with color coordinates (0.18, 0.13). In other words, BD4PP molecule inhibited the intermolecular interaction, resulting in color purity and high efficiency by introducing xylene units into the structure.
저자 박지현1, 김윤희1, 정성준2, 손선영2, Xinwei Wu1, 박광훈1, 안형주3, 권순기1
소속 1경상대, 2포항공대, 3포항가속기(연)
키워드 Blue fluorescence; Pyrene; Color purity
E-Mail