| 학회 |
한국고분자학회 |
| 학술대회 |
2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터) |
| 권호 |
44권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Sulfoxide-based vinyl group protection strategy: A Facile post-polymerization modification method |
| 초록 |
We report the introduction of a vinyl group into a polymer simply through the sulfoxide-based protection-deprotection, for the first time to our best knowledge. When sulfoxides are present next to an electron withdrawing groups, they can be easily removed with heat, forming vinyl groups. Based on this concept, we protected the alpha site of methacrylate with phenyl sulfoxide which can be thermally deprotected to form a methacrylic group. To prove this concept, we synthesized sulfoxide-protected (SP) polymers via ATRP using specifically designed SP monomer and initiator. The methacrylate-functionalized polymers were prepared by deprotecting the SP-polymers at 110 oC in anisole. The polymers were characterized by SEC, 1H NMR spectroscopy, MALDI-TOF-MS and ESI-Q-TOF MS. The vinyl functionality was confirmed as more than 96%. This concept exhibits an efficient way to introduce vinyl group into polymer with a great potential in macromolecular engineering. |
| 저자 |
김동우1, 도주혁1, 이하나2, 강유영2, 전흥배2, 백현종1
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| 소속 |
1부산대, 2광운대 |
| 키워드 |
vinyl group modification; protection-deprotection; macromonomer; atom transfer radical polymerization (ATRP)
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| E-Mail |
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