화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 기능성 고분자
제목 Synthesis of Superhydrophobic Copolymer/Silica Core/Shell Particles
초록 Silica-coated polymeric particles were synthesized based on the cationic colloidal particles which were prepared by precipitation polymerization of Divinylbenzene(DVB) in the presence of a cationic monomer, dimethylaminopropyl methacrylamide(DMAPMA) using 2,2'-Azobisisobutyronitrile(AIBN) as an initiator. Negatively charged silica precursors were rapidly hydrolyzed onto the cationic surfaces of colloidal particles. The resulted poly(DVB-co-DMAPMA)/silica core/shell particles were characterized by scanning electron microscopy (SEM). Then, the fabrication of a superhydrophobic particle surface was achieved by coupling reaction of the poly(DVB-co-DMAPMA)/silica core/shell particle surface with nonafluorohexyltriethoxysilane. The water static contact angle on the surface of epoxy layer with rough microstructures was investigated on a contact angle system.
저자 고소희, 황하수, 최경호, 박인
소속 한국생산기술(연)
키워드 superhydrophobic; precipitation polymerization; core-shell; polymer particles
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