학회 | 한국고분자학회 |
학술대회 | 2004년 가을 (10/08 ~ 10/09, 경북대학교) |
권호 | 29권 2호, p.40 |
발표분야 | 기능성 고분자 |
제목 | Phase behaviors of Solid Polymer Electrolytes/Salt System in lithium secondary battery by Group-Contribution Method: Applicability of Modified Double-Lattice Model with Pressure Effect. |
초록 | A new group-contribution model based on the modified double-lattice theory with the volume effect is developed and applied to describe phase-behaviors of solid polymer electrolyte/salt with various pressure. The proposed model includes the van der Waals energy contribution from dispersion and polar force. Our result show that an eutectic point moves toward a higher Tm and lower weight fraction of salt significantly decreases with pressure. Quantitative descriptions according to the proposed model are in good agreement with the experimental data for the given systems. |
저자 | 주재호1, 배영찬2 |
소속 | 1한양대, 2서울시 성동구 행당 1동 한양대 |
키워드 | group-contribution; modified double-lattice theory; solid polymer electrolyte/salt; phase-behaviors; Pressure Effect |