초록 |
Self-assembly of nanoparticles and amphiphilic polymers offers a way to control the organization and properties of functional nanoparticles and polymers. Recently, we found that nanoparticles play an active role in the binary self-assembly and they can significantly impact the co-assembly structure. We have demonstrated that three distinct assembly structures can be obtained by controlling the polymer-nanoparticle interactions: polymersomes densely packed with nanoparticles (magneto-polymersomes), core-shell type polymer assemblies where nanoparticles are radially arranged at the interface between the polymer core and the shell (magneto- core shell), and polymer micelles where nanoparticles are homogeneously incorporated (magneto-micelles). Furthermore, we utilized air-liquid interfacial self-assembly to create nanoparticle/polymer composite film. In this presentation, we will discuss what affects the binary self-assembly and how to control their morphologies. |