화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2910
발표분야 에너지
제목 Effects ofCarbon Coatingon The Electrochemical Performance of Spinel-type Li4Ti5O12 as an Anode Material for Lithium-ion Batteries
초록 The lithium titanate spinel Li4Ti5O12 is gaining more and more attention as anode materialsfor lithium secondary batteries. As the main feature of the compounds, spinel-type lithium titanatehas their unique insertion-deinsertion mechanism that involves a two-phase processwith the same symmetry. However, the low rate capability resulting from low electronic conductivity hindered the practical use of Li4Ti5O12.
The effects ofcarbon coatingon the electrochemical properties of spinel-type Li4Ti5O12/C were systematically investigated. The experimental results showed that thesecoatingimproved the reversible capacity and cycling stability over the pristine Li4Ti5O12.
Phase purity of the synthesized materials was identified by the X-ray diffraction(XRD) and scanning electron microscopy(SEM). The charge and discharge capacities were measured with coin cells in which lithium metal foil was used as the counter electrode.
저자 김주빈1, 조병원2, 변동진1, 정경윤2
소속 1고려대, 2KIST 이차전지연구센터
키워드 battery; li; lto; anode
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