| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Tunable Superhydrophobic and Optical Properties of Colloidal Films Coated with Block Copolymer Micelle/Micelle Multilayers |
| 초록 |
BCM multilayers are formed onto silica colloidal particles taking advantage of the complementary interactions between polystyrene-block-poly(4-vinylpyrine) (PS-b-P4VP) and polystyrene-block-poly(acrylic acid) (PS-b-PAA). The adsorption of fluoroalkylsilane polymers onto these (PS49.5K-b-P4VP16.5K/PS16K-b-PAA4K)3-coated colloidal films yields the superhydrophobic properties with high water droplet contact angle above 170o and we demonstrate that their superhydrophobicity could be easily tuned by the surface morphology of the adsorbed BCM multilayers. Additionally, hydrophobic quantum dots and fluorescent dyes were incorporated into the hydrophobic PS core of the BCMs for the superhydrophobic films to reveal with optically tunable properties. The reported hierarchical approach offers new opportunities to prepare the smart superhydrophobic surfaces with controllable nanostructure and desired optical properties. |
| 저자 |
홍진기1, 조진한2, 차국헌1
|
| 소속 |
1서울대, 2국민대 |
| 키워드 |
layer-by-layer; micelle; block copolymer; superhydrophobic; quantum dot
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| E-Mail |
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