화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 봄 (04/25 ~ 04/27, 제주 ICC)
권호 18권 1호, p.1137
발표분야 촉매
제목 Shape effect of CuO in inverse CuO@CeO2 catalysts for PROX reaction 
초록  The reactivity depends on the crystal plane of the catalyst for structure-sensitive reactions. Thus, controlling the shape of nanoparticles is important aspect of desired catalyst synthesis. Nowadays, synthesis of the shape-controlled CuO has attracted considerable attention as substitute catalysts due to the cost and limited availability of precious metal. Copper with excellent catalytic property is used as catalysts in copper-ceria systems for PROX (preferential oxidation) reaction. Recently, inverse model catalysts of CeOx nanoparticles supported over Cu have shown a high catalytic activity in PROX reaction. In this study, sheet-like nanostructure of CuO was synthesized. Ceria was deposited on sheet-like CuO supports. The catalytic activity and selectivity of CeO2/CuO catalysts with CuO nanosheet were evaluated for PROX reaction. This catalyst was characterized by TEM, SEM, XRD.
저자 김지연, 권용우, 이현주
소속 연세대
키워드 shape control; copper oxide; PROX reaction
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