화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-촉매
제목 Correlating the Effect of Surface Termination Groups of Titanium Carbide MXenes with the Resulting Electrocatalytic Performance for the Oxygen Reduction Reaction
초록 MXenes with 2D layered structure possess attractive metallic conductivity, and stability for application in electrocatalysis. Here, we investigate the promise of Ti3C2 as supports for the Pt-driven 4-electron-driven oxygen reduction reaction (ORR) in the development of polymer electrolyte membrane fuel cells (PEMFC). Following the dealumination treatment of corresponding MAX parent materials in the presence of HF, the resulting MXene phase revealed interplanar mesoporosity. The obtained 2D materials were then exfoliated in TMAOH and characterized through SEM, TEM, ICP, XPS, and XRD analyses. The nature of the resulting surface functional groups is currently under investigation as a result of the selected synthesis steps. Our preliminary results are expected to shed light on the resulting interaction of Ti3C2 with Pt, and on the resulting electrocatalytic ORR activity and stability of these systems.
저자 홍혜지1, Filipe Marques Mota1, Nur Aqlili Riana Binti Che Mohamad1, 조원일2, 김동하1
소속 1이화여자대, 2한국과학기술(연)
키워드 MXene; ORR; PEMFC; Sureface termination
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