| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
기능성 고분자 (포스터발표만 진행) |
| 제목 |
Synthesis of functionalized PEO-based macromonomer |
| 초록 |
It has been well known that potassium alkoxide is very efficient initiator to polymerize ethylene oxide by following a living monomer. In this experimental, Potassium bis(trimethylsilyl)amide as an initiator was used to synthesize poly(ethylene oxide) bearing α-amino functional group via in THF at 40°C for 24h. After complete polymerization of ethylene oxide, methacryloylchloride was delivered in the presence of triehylamine into the reactor via a break seal technique under high vacuum leading to generation of α-amino functionalized PEO-macromonomer. The as-synthesized α,ω-heterotelechelic poly(ethylene oxide) could be successfully synthesized for preparation of functionalized PMMA-g-PEO copolymer. In this presentation, we will discuss the preliminary results for the experiment. |
| 저자 |
양세라, 김정안, 이재열, 강호정, 이재혁, 김윤, 연규상, 김성우, 이유라
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| 소속 |
경희대 |
| 키워드 |
poly(ethylene oxide); functionalized polymer
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| E-Mail |
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