화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 대학원생 구두발표 (발표15분)
제목 Consecutive Phase Separation of Cholesteric Liquid Crystals in Emulsion Drops for Photonic Capsules with Multiple Photonic Bandgaps
초록 Cholesteric liquid crystals (CLCs) construct a helical superstructure which exhibits photonic bandgap due to its periodic modulation of refractive index along the helical axis. Micro-compartments of CLCs make use of this photonic property for applications such as sensing, lasing, and optical barcoding. To provide enhanced functionality, the integration of distinct CLCs into a single microgranule can be performed. However, it is challenging to fabricate multishell structure of CLCs without a complicated microfluidics system. Here, we suggest a facile and spontaneous production of CLC multishells through liquid-liquid phase separation (LLPS). The multiplicity of emulsions is controlled from one to five by adjusting the initial composition of the ternary mixture. The chiral dopant is unevenly partitioned in CLC-rich layers in an odd yet expected manner during LLPSs. The resultant single microgranules embrace distinct stopbands in CLC-rich layers enabling dual-band-edge lasing.
저자 박시훈1, 이상석2, 김신현1
소속 1한국과학기술원, 2한국과학기술(연)
키워드 cholesteric liquid crystals; photonic shells; liquid-liquid phase separation; multiple emulsions
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