화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터)
권호 20권 1호, p.470
발표분야 에너지
제목 Hydrogen production from low temperature WGS reaction over co-precipitated Cu–Ce(1–x)Zr(x)O2 catalysts
초록 Water-gas shift (WGS) reaction has been carried out at the gas hourly space velocity of 72,152 h–1 over Cu–Ce(1–x)Zr(x)O2 catalyst prepared by a co-precipitation method. The CeO2/ZrO2 ratio was systematically varied to optimize Cu–Ce(1–x)Zr(x)O2 catalysts. Cu–Ce0.8Zr0.2O2 exhibited the highest CO conversion as well as the most stable activity (XCO > 41% at 320 oC for 25 h). The excellent catalytic performance is mainly due to a strong metal to support interaction, resulting in the prevention of Cu sintering.
저자 정대운1, 나현석1, 장원준1, 한원비1, 노현석1, 정운호2, 윤왕래2
소속 1연세대, 2한국에너지기술(연)
키워드 Water-gas shift; CeO2/ZrO2 ratio; Strong metal to support interaction; Cu sintering
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