| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Synthesis and property of Novel Conjugated Polymers based on Benzodithiophene and Fluorinated Phenazine for PSCs |
| 초록 |
PBDT-DT-DoDFPz and PBDT-DT-DHDFPz were synthesized using stille coupling reaction. These polymers were expected that various change of property. These polymers showed that λmax in the absorption spectrum was 575nm to 591nm in the CB solution. The polymer absorption in the film state was red shifted to about 16nm to 35nm. PBDT-DT-DoDFPz was red-shifted than PBDT-DT-DHDFPz. The reason this phenomenon was appeared is an effect of linear alkyl side chain. PBDT-DT-DoDFPz that had a linear alkyl side chain was better packed in the film than the PBDT-DT-DHDFPz with a branched alkyl side chain. A TGA (thermogravimetric analysis) figure showed that the 5% weight-loss temperature (Td) of these polymers were over 330℃ under an inert nitrogen. The HOMO (highest occupied molecular orbital) energy level of -5.27 ~ -5.37eV. Branched phenazine units had deeper HOMO energy level then linear phenazine units. PBDT-DT-DoDFPz achieved 3.41% of PCE (power conversion efficiency) and 0.66V of Voc. |
| 저자 |
임종진, 이근대, 박성수, 이원기, 진영읍
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| 소속 |
부경대 |
| 키워드 |
PSCs; OPVs
|
| E-Mail |
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