화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터)
권호 14권 2호
발표분야 석유화학.윤활유
제목 Dehydrocyclization of 1,4-Butanediol over Copper-based Catalysts
초록 Copper-based catalysts containing two or three components were synthesized by co-precipitation method. Copper-based catalysts were characterized through N2 adsorption, XRD, N2O titration, temperature- programmed reduction, and temperature-programmed desorption of ammonia. Effect of promoter on dehydrocyclization of 1,4-butanediol over copper-based catalysts was investigated in a fixed bed reactor.Catalytic activity of copper was greatly affected by the promoters. Some oxides showed the higher additive effect for the γ-Butylolactone synthesis with enhancing dehydrogenation ability of metallic Cu and enlarging Cu surface area.
저자 이윤정1, 전종기1, 고영수1, 윤영식2, 오승훈2
소속 1공주대, 2(주) SK 에너지
키워드 Dehydrocyclization
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