학회 |
한국고분자학회 |
학술대회 |
2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO)) |
권호 |
45권 1호 |
발표분야 |
분자전자 부문위원회 I |
제목 |
New Triad-Type, Multi-Functional Compatibilizers for Enhancing Device Efficiency and Thermal/Mechanical Stabilities of Polymer Solar Cells |
초록 |
In this work, we report a new acceptor–donor–acceptor (A–D–A) triad-type small molecule, 5TRh-PCBM, for use as a compatibilizer in enhancing the thermal stabilities and mechanical properties of efficient polymer solar cells (PSCs). This multifunctional 5TRh-PCBM molecule, consisting of an oligothiophene segment as the central core and fullerene derivatives as the end groups, is designed to enable strong interactions between the 5TRh-core with various types of efficient polymer donors containing thiophene or fused-thiophene units, while the end fullerene groups preferentially interact with PCBM acceptors. To examine the effectiveness of this molecular compatibilizer, PSCs with different donors (PTB7-Th, PBDB-T, and P3HT) have been fabricated and tested, with the addition of various amounts of 5TRh-PCBM. The addition of 5 and 10 wt% of 5TRh-PCBM significantly enhances the thermal and mechanical stabilities of all these PSCs. |
저자 |
김건우1, 이영웅2, 우한영2, 김범준3, 마부수3, 김진석3, 박진수3, 이승진3, Thanh Luan Nguyen2, 송명3, 김택수3
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소속 |
1KAIST, 2고려대, 3한국과학기술원 |
키워드 |
polymer solar cells; compatibilizer; phase separation; thermal stability; mechanical robustness
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E-Mail |
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