화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 분자전자 부문위원회 I
제목 New Triad-Type, Multi-Functional Compatibilizers for Enhancing Device Efficiency and Thermal/Mechanical Stabilities of Polymer Solar Cells
초록 In this work, we report a new acceptor–donor–acceptor (A–D–A) triad-type small molecule, 5TRh-PCBM, for use as a compatibilizer in enhancing the thermal stabilities and mechanical properties of efficient polymer solar cells (PSCs). This multifunctional 5TRh-PCBM molecule, consisting of an oligothiophene segment as the central core and fullerene derivatives as the end groups, is designed to enable strong interactions between the 5TRh-core with various types of efficient polymer donors containing thiophene or fused-thiophene units, while the end fullerene groups preferentially interact with PCBM acceptors. To examine the effectiveness of this molecular compatibilizer, PSCs with different donors (PTB7-Th, PBDB-T, and P3HT) have been fabricated and tested, with the addition of various amounts of 5TRh-PCBM. The addition of 5 and 10 wt% of 5TRh-PCBM significantly enhances the thermal and mechanical stabilities of all these PSCs.
저자 김건우1, 이영웅2, 우한영2, 김범준3, 마부수3, 김진석3, 박진수3, 이승진3, Thanh Luan Nguyen2, 송명3, 김택수3
소속 1KAIST, 2고려대, 3한국과학기술원
키워드 polymer solar cells; compatibilizer; phase separation; thermal stability; mechanical robustness
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