학회 | 한국화학공학회 |
학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
권호 | 22권 2호, p.1916 |
발표분야 | 에너지 |
제목 | Electrochemical properties of microporous carbon as an electrode for supercapacitor prepared by triazine based conjugated microporous polymer |
초록 | In this study, we demonstrate a facile strategy for the design and synthesis of regular microporous carbon nanoparticle as an electrode for high performance supercapacitor. Microporous carbon particle were fabricated using novel organic polymer synthesized simple Friedel-Craft method which was for the first time synthesized by cyanuric chloride and 1,3,5-triphenylbenzene in dichloromethane (DCM) under solvothermal condition at 70 oC using anhydrous aluminium chloride as a catalyst. After synthesis, the attained sample was carbonized in tubular furnace at 700, 800, and 900 oC with nitrogen and carbon dioxide atmosphere, respectively. Microporous carbon nanoparticle carbonized at 800 oC as a supercapcitor electrode showed unique capacity behavior (389 F/g at 1 A/g) and excellent cycling stability (98 % retention after 1000 cycles at 1 A/g) in 6 M KOH aqueous electrolyte. Acknowledgement: This study was supported by the National Research Foundation of Korea (grant no.: NRF-2015R1A4A1042434). |
저자 | 김민재, 천영걸, 이은수, 심상은 |
소속 | 인하대 |
키워드 | 에너지 소재 |
원문파일 | 초록 보기 |