화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 고분자구조 및 물성
제목 Fabrication of Surface Crosslinked Superabsorbent Polymers (SAPs) using Polycations
초록 Superabsorbent polymer (SAP) is a hydrogel that can absorb and retain large volumes of water and aqueous solutions. SAP usually using in diapers, has requires various mechanical properties. Especially, due to the main characterization of the diaper, SAP needs to withstand high pressure and have high permeability to suppress the gel-blocking phenomenon. In our study, we fabricated the acrylic acid based spherical SAP through the Inverse-suspension polymerization of the partially neutralized acrylic acid monomers with internal crosslinkers. These manufactured spherical SAPs have high water retention capacity, but low elastic modulus and poor permeability. Therefore, we tried to surface crosslink using polycations on the spherical SAP particles to improve the mechanical properties and thus producing a core-shell structure.
저자 이경민, 윤병주, 김세민, 강성민, 김지영, 함정우, 고원건
소속 연세대
키워드 Superabsorbent polymer; Hydrogel; Inverse-suspension polyemrization; surface crosslinking; polycations.
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