화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 고분자구조 및 물성
제목 Facile Fabrication of Porous PVDF-HFP Thin Film as Separator for Lithium-Ion Batteries
초록 Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) membranes have been receiving attentions because of their widely potential applications in many fields. The production of PVDF-HFP membrane with highly controlled porosity in a scalable and cost-effective way is crucially necessary. In this work, we report on the fabrication of PVDF-HFP membrane by facile single-step solution-immersion dip-coating method. Herein, the porous membrane is generated based on the concept of evaporation-induce phase separation of a ternary solution which composes of polymer in a mixture of acetone and water as solvent/nonsolvent pair. The porous film showed the multi-layered honeycomb-like cellular structure. The structural morphology and porosity of the membrane can be regulated by changing solution composition or drying conditions. Gel polymer electrolytes composed of PVDF-HFP microporous membrane incorporating BMIMTFSI:LiTFSI are characterized as the electrolytes in lithium-ion batteries.
저자 Van-Tien Bui1, Umapathi Reddicherla2, 김현석2, 김종헌2, 최호석2
소속 1Chungnam National Univ., 2충남대
키워드 Sponge-like; PVDF-HFP; Separator; Li-ion battery
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