화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자합성
제목 Synthesis and Photophysical Properties of Trimethylsilyl Containing Hyperbranched Conjugated Poly(para-phenylene vinylene) Derivatives
초록 Conjugated polymers have emerged as viable electronic materials for numerous applications. So far, the majority of work on conjugated polymers has been focused on linear one-dimensional polymers. Although a few of two-dimensional conjugated polymers, such as hyperbranched conjugated polymer have been reported to exhibit comparable charge transferring and processing properties to their linear counterparts, two-dimensional conjugated polymeric light-emitting materials have been less discussed in the literature. Here, we report the synthesis and light-emitting properties of trimethylsilyl containing hyperbranched conjugated poly(para-phenylene vinylene) derivatives through A2 and B3 type monomer. A synthesized trimethylsilyl containing hyperbranched polymer showed pure blue emission as film state at 457 nm in photoluminescence (PL) measurement and was found to showing almost no excimer emission peak even the polymer film was annealed at 80 °C.
저자 양훈주1, 이재민2, 안 택1
소속 1경성대, 2한국화학(연)
키워드 Conjugated polymer; hyperbranched polymer; light-emitting material; Poly(para-phenylene vinylene) Derivative
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