화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 기능성 고분자
제목 Optimized Conditions for High Performance of Thin Film Composite Reverse Osmosis Membranes
초록 Forty-two Thin Film Composite Reverse Osmosis (TFC RO) membranes were prepared under various concentrations of m-phenylenediamne (MPD) in water and trimesoly chloride (TMC) in hexane (MPD/TMC monomer ratio from 2.5 to 150) using interfacial polymerization (IP) to understand the relationship of membrane performance with the physicochemical properties such as surface properties, film thickness, chemical structure and density. SEM analysis was used to confirm the surface morphologies of the obtained TFC RO membranes, and AFM analysis was used to obtain the surface area and the thickness of the polyamide selective layer. Water flux and salt rejection of TFC RO membranes were measured under 16 bar at 25 °C in cross-flow typed equipment. The best performance of 55 LMH of salt water flux and 99% of salt rejection were obtained in the concentration of 1.0 wt.% of MPD and 0.025 wt.% of TMC (40 of MPD/TMC ratio).
저자 박상희1, 조진한2, 이정현2, 황승상1, 백경열1
소속 1한국과학기술(연), 2고려대
키워드 TFC RO membrane; monomer concentration; interfacial polymerization; surface property; thickness; density
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