화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.2197
발표분야 촉매 및 반응공학
제목 Importance of the Hydrocracking Catalyst and Separate Deoxygenation/Hydrocracking Steps for Maximizing Biojet Fuel Production from Triglyceride
초록 Various parameters in the catalytic hydroconversion of triglycerides were investigated for maximizing the production of biojet fuel. The results demonstrated that the two-step reaction process composed of separate hydrotreating/hydrocracking steps is more advantageous than the single-step process in terms of high biojet fuel yield, suppressed production of aromatic compounds, and long catalyst lifetime. In the two-step process, the diffusion characteristics of the multibranched hydrocarbon in the hydrocracking catalysts could be correlated with the biojet fuel yields and the iso/n-paraffin ratios. Consequently, Pt supported on nanocrystalline large-pore BEA zeolite produced the largest biojet fuel yield with highest iso-paraffin content as a result of suppressed overcracking. Under the optimized conditions, 55 wt% of biojet fuel with respect to palm oil was achieved after final distillation, which satisfied all the required fuel specifications.
저자 최민기1, 김명엽1, 김재곤2, 이미은2, 이송현1
소속 1한국과학기술원, 2한국석유관리원
키워드 촉매 및 반응공학
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