학회 |
한국화학공학회 |
학술대회 |
2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
권호 |
23권 2호, p.2197 |
발표분야 |
촉매 및 반응공학 |
제목 |
Importance of the Hydrocracking Catalyst and Separate Deoxygenation/Hydrocracking Steps for Maximizing Biojet Fuel Production from Triglyceride |
초록 |
Various parameters in the catalytic hydroconversion of triglycerides were investigated for maximizing the production of biojet fuel. The results demonstrated that the two-step reaction process composed of separate hydrotreating/hydrocracking steps is more advantageous than the single-step process in terms of high biojet fuel yield, suppressed production of aromatic compounds, and long catalyst lifetime. In the two-step process, the diffusion characteristics of the multibranched hydrocarbon in the hydrocracking catalysts could be correlated with the biojet fuel yields and the iso/n-paraffin ratios. Consequently, Pt supported on nanocrystalline large-pore BEA zeolite produced the largest biojet fuel yield with highest iso-paraffin content as a result of suppressed overcracking. Under the optimized conditions, 55 wt% of biojet fuel with respect to palm oil was achieved after final distillation, which satisfied all the required fuel specifications. |
저자 |
최민기1, 김명엽1, 김재곤2, 이미은2, 이송현1
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소속 |
1한국과학기술원, 2한국석유관리원 |
키워드 |
촉매 및 반응공학 |
E-Mail |
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VOD |
VOD 보기 |
원문파일 |
초록 보기 |