| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
Crystal Engineering of Organic Methylquinolinium Crystals with Various Benzenesulfonate Anions for Photonic Applications |
| 초록 |
We investigated ionic-type electro-optic crystals based on HMQ (2-(4-hydroxy-3-methoxystyryl)-1-methylquinolinium) cation and various benezenesulfonate anions. Acentric HMQ-T (2-(4-hydroxy-3-methoxystyryl)-1-methylquinolinium 4-methylbenzenesulfonate) and HMQ-OH (2-(4-hydroxy-3-methoxystyryl)-1-methylquinolinium 4-hydroxybenzenesulfonate) crystals exhibited large macroscopic nonlinear optical and electro-optic properties in the solid state. In order to obtain HMQ crystals suitable for THz wave generation, bulk HMQ crystals were grown by slow and rapid cooling methods in solution. HMQ-T and HMQ-OH showed acentric monoclinic space group Pn and Pc, respectively. To modify the crystal characteristics of HMQ crystals, various solution growth methods in different solvents were investigated. Efficient THz wave generation based on HMQ crystals by controlling crystal thickness were demonstrated at a pumped wavelength of 800 nm. |
| 저자 |
이승헌, 김지수, 권오필
|
| 소속 |
아주대 |
| 키워드 |
electro-optic; ionic-type crystals; THz wave
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| E-Mail |
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