화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터)
권호 14권 2호
발표분야 환경.에너지
제목 Immobilization of carbonic anhydrase-gold nanoparticle on mesoporous silica: Its nanobiocatalytic activity for hydrolysis of p-nitrophenyl acetate
초록 Ultra-large mesoporous silica materials were synthesized with the use of triblock copolymers P123 and TMB under acidic conditions and characterized by XRD, BET, Si NMR, FESEM, HRTEM and Zeta potential. The mesoporous silica was chemically modified with SH, -NH2 and CN group to implant gold nanoparticles for immobilization of carbonic anhydrase (CA). Importantly, here the quantity of adsorbed CA is enhanced by immobilization over the positive charge gold nanoparticle. The nanobiocatalytic activity of this CA was performed towards the hydrolysis of p-nitrophenyl acetate. The pH, temperature, reusability and storage stability of this nanobiocatalyst is well applauded.
저자 Mari Vinoba1, 김대훈1, 임경수1, 정순관1, Muthukaruppan Alagar2
소속 1한국에너지기술(연), 2Department of Chemical Engineering
키워드 Mesoporous silica; gold nanoparticles; carbonic anhydrase; nanobiocatalyst; immobilization; kinetics
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