화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스))
권호 10권 2호
발표분야 촉매
제목 The characterization of Pd/C catalysts and their effects on the reaction network in biphenol hydrogenation
초록 Pd/C catalysts were prepared from different methods and their effects were compared in biphenol hydrogenation. The catalysts were characterized by XPS, TEM, XRD, OHTC (oxygen-hydrogen titration methods). In biphenol hydrogenation, C=C bond hydrogenation was performed preferentially followed by C=O bond hydrogenation. The initial activity(C=C hydrogenation) and the yield to BHD, the final product, were different from the selection of the catalysts. The textural structure of support, distribution of palladium metal on the support, the range of particle size seemed to be the main factors in determining the catalyst performance.
저자 조홍백, 박융호
소속 한양대
키워드 characterization; Pd/C; biphenol hydrogenation; reaction network
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