| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
무기재료_포스터 |
| 제목 |
New inorganic/organic hybrid fibers exhibiting catalytic and permanent birefringence behaviors |
| 초록 |
It is still rare to find inorganic semiconductors that can be stabilized as a solution form. If available, such a behavior can be widely applied for practical applications. In this work, we report one-dimensional inorganic semiconductors APdPS4 (A = Na, K) can be solubilized in polar organic solvents and 1∞[PdSP4-] anions form nanowires. Such nanowires form environmentally stable, flexible inorganic/organic polymeric hybrid fibers by reacting with specific polymers. Nanowire structure is intact in hybrid fibers. Such hybrid fibers show unusual physical and chemical properties that are not observed from bulk KPdPS4. They exhibit permanent birefringence and excellent catalytic properties, for example, cross-coupling reaction that is a versatile route to aryl compounds for pharmaceuticals and find chemicals, due to the presence of 1∞[PdSP4-] nanowires |
| 저자 |
김한울1, 오영탁2, 김상욱3, 정인4
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| 소속 |
1School of Chemical and Biological Engineering, 2Seoul National Univ. / Center for Nanoparticle Research, 3Institute of Basic Science, 4Department of Materials Science and Engineering |
| 키워드 |
hybrid fibers; birefringence; semiconductor
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| E-Mail |
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