학회 |
한국공업화학회 |
학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
권호 |
22권 2호 |
발표분야 |
(국제협력위원회) 우수외국인연구자세션 |
제목 |
Controllable Synthesis and Catalytic Activities of Gold Multipod Nanoparticle Cores and NMOF-Derived Shell Nanohybrids |
초록 |
We report a facile fabrication of gold multipod nanoparticles (GMNs) embedded within cobalt sulfide nanocage. Specifically, the as-prepared GMN cores- ZIF-67 shell (GMN@ZIF-67) nanostructures are precursors for the preparation of unique nanohybrids composed of multiple GMNs and cobalt sulfide (GMN@CoxSy) nanocages. This is an unusual example how anisotropic noble metal nanoparticle cores-inorganic cage-like shells nanohybrids derived from NMOFs can be prepared. The insertions of GMNs into cobalt sulfide nanocages can result in a substantially higher OER activity of GMN@CoxSy nanocages (345 mV) compared with those of GMNs (617 mV) and CoxSy nanomaterials (418 mV) at the current density of 10 mA cm-2. The enhanced OER performance of GMN@CoxSy nanocages is mainly attributed to the synergistic effect between the GMN cores and cage-like cobalt sulfide shells. |
저자 |
MAIDUYHIEN, 유효종
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소속 |
한림대 |
키워드 |
Gold Multipod Nanoparticle; NMOFs; Core-Shell; Synergistic Effect; OER
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E-Mail |
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