화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.704
발표분야 열역학
제목 Liquid-liquid equilibria of polymer solutions: Associated Flory Huggins Theory
초록 We developed a new Flory-Huggins model by adding a specific interaction parameter which is from modified double-lattice model for Helmholtz energy of mixing for the binary liquid mixtures. This model is very simple and easy to the engineering application. Using the proposed model, we can successfully describe the phase behaviors of polymer solutions having an upper critical solution temperature (UCST), a lower critical solution temperature (LCST), both UCST and LCST, and a closed miscibility loop.It is found that our model shows fitting well to the experimental data of the real complex phase behavior of polymer solutions
저자 정재경, 배영찬
소속 한양대
키워드 Flory-Huggins Theory; specific interaction; Liquid-liquid equilibria
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