학회 |
한국고분자학회 |
학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
권호 |
41권 1호 |
발표분야 |
기능성 고분자 |
제목 |
Formation of Conjugated Oligomer Nanorods by Assembling with 2-Bromobenzaldehydeand Phospholipid |
초록 |
Conjugated oligomer nanorods were prepared by shattering phase-separated films of the conjugated oligomer, 2-bromobenzaldehyde (2-BBA) and a phospholipid. 2-BBA was assembled with the conjugated oligomer, thienoisoindigo ethylhexyl-bezene, (T2GEH-bz), via halogen bondings between electron rich halogen atoms and electron poor carbonyl groups in 2-BBA and T2GEH-Bz and via close packing of alkyl chains together with fullfilling empty space with 2-BBA. It was observed that pi-pi stacking of conjugated planes were improved with increasing the ratio of 2-BBA and with decreasing that of the lipid to the oligomer, as proven bathochromic shifts in absorption spectra. End results were water-dispersed nanorods of the conjugated oligomer, a near infrared absorbent for photoacoustic imaging and photothermal cancer therapy. |
저자 |
노주란1, 조혜진2, 강효진2, 양창덕2, 박주현1
|
소속 |
1중앙대, 2UNIST |
키워드 |
Conjugated oligomer; nano rod; nano structure
|
E-Mail |
|