| 학회 |
한국고분자학회 |
| 학술대회 |
2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO)) |
| 권호 |
44권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Polystyrene and Poly(4-hydroxystyrene)-containing Bottlebrush Block Copolymers Featuring Structural Coloration |
| 초록 |
Self-assembly of block copolymers (BCPs) has recently received attention as a promising application for photonic crystals due to simple fabrication processes and vivid structural coloration. To generate bright structure colour in visible range, BCPs with high molecular weights (MWs ＞ 400 kDa) and narrow dispersity are typically used in one-dimensional photonic crystals (1D PhCs). However, the applicability of such BCP is hindered by difficult synthesis and chain-entanglement during self-assembly. Thus, bottlebrush block copolymers, which feature less chain entanglement and ultrahigh MWs, can provide better opportunity to create 1D PhCs. In this work, we present the facile synthesis of bottlebrush block copolymers (BBCPs) including polystyrene and poly(4-hydroxystyrene) via ‘grafting-through polymerization’ and acid-catalysed hydrolysis. Additionally, 1D PhC films were fabricated by their self-assembly and controlled by blending with hydrogen-bond accepting organic additives. |
| 저자 |
유용군1, 서춘희2, 채창근1, 김명진1, 서호빈1, 강영종2, 이재석1
|
| 소속 |
1광주과학기술원, 2한양대 |
| 키워드 |
living anionic polymerization; ROMP; bottlebrush block copolymers
|
| E-Mail |
|
