화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 Synthesis of electrically conductive polyethylene-octene elastomer/polyaniline composites for an electroactive actuator
초록 Electrically driven shape memory composites based on polyethylene-octene elastomer(POE) and polyaniline(PANi) were prepared by inverted emulsion method. Polymerization of aniline was carried out in a solution of POE/toluene as the continuous phase with dodecylbenzene sulfonic acid as the dopant. Dicumyl peroxide(1phr) was added into the composites, and the dried composites were then cured at 150℃ for 10min. EDX-SEM reveals that PANi was dispersed uniformly in the POE matrix. DSC reveals the composites have a melting transition at 40℃. When the content of PANi was 60wt%, the electrical conductivity of the composite increased to 1.40ⅹ10-3 S/cm. The percolation threshold was found to be at the vicinity of 40wt% PANi content. The blends exhibited a voltage-triggered shape memory effects.
저자 박광균, 장영욱, 김용재, 이재은, 구용성
소속 한양대
키워드 Polyethylene-octene elastomer(POE); Polyaniline(PANi); electrical conductivity; shape memory effects
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