화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 기능성 고분자
제목 Self-healing and high stretchable poly(lithium acrylate)-based hydrogels for supercapacitor applications
초록 Stretchable and self-healing properties are highly required for wearable and flexible energy storage devices such as supercapacitors. On the other hand, the drawback between high ionic conductivity and mechanical performance still becomes the typical problem to overcome. In this report, high stretchable and self-healing poly(lithium acrylate)-based hydrogels were prepared with free radical polymerization of lithium acrylate with vinyl silica nanoparticles as cross-linker and ammonium persulfate as initiator. Lithium acrylate was prepared by ion-exchanging acrylic acid with lithium hydroxide. Vinyl silica nanoparticles as cross-linkers acting as a stress buffer contribute to strengthening the polymer network under strain. Meanwhile, the self-healing ability is due to intramolecular and intermolecular hydrogen bonding of the hydrogel. Self-healing hydrogel polymer electrolytes were able to stretch up to 2000% and possessed high ionic conductivity ~10-3 S/cm at room temperature.
저자 Puji Lestari, 최우혁
소속 인하대
키워드 Self-healing; hydrogel; solid polymer electrolyte
E-Mail