화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2003년 가을 (10/10 ~ 10/11, 부경대학교)
권호 28권 2호, p.107
발표분야 고분자 합성
제목 Ethylene Polymerizations with Dimeric (α-Diimine)nickel(II) Catalysts
초록 Dimeric α-diimine ligands with controled aryl substituents were synthesized from acenaphthenequinone via sequential dehydration with aromatic amines. The α-diimine ligands were combined with nickel precursor to form new dimeric (α-diimine)nickel(II) catalysts. The catalysts were subjected to ethylene polymerizations with MAO cocatalyst. The effect of dimeric structure of the (α-diimine)nickel catalysts and physical properties of the polyethylene obtained will be discussed.
저자 전만성, 김상율
소속 한국과학기술원 화학과 분자과학사업단(BK21) & 기능성고분자연구센터
키워드 Ethylene; Polymerization; Nickel; Diimine
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