| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
고분자가공/복합재료 |
| 제목 |
Engineering the Shape of Block Copolymer Particles by Surface-Modulated Graphene Quantum Dots |
| 초록 |
10 nm-sized graphene quantum dots (GQDs) are shown to be efficient surfactants for producing 3-pentadecyl phenol (PDP)-combined poly(styrene-b-4-vinylpyridine) (PS-b-P4VP(PDP)) particles that feature tunable shapes and internal morphologies. The surface properties of GQDs were modified by grafting different alkyl ligands, such as hexylamine and oleylamine, to generate the surfactant behavior of the GQDs. In stark contrast to the behavior of the unmodified GQDs, hexylamine-grafted GQDs and oleylamine-grafted GQD surfactants were selectively positioned on the PS and P4VP(PDP) domains, respectively, at the surface of the particles. This positioning effectively tuned the interfacial interaction between two different PS/P4VP(PDP) domains of the particles and the surrounding water during emulsification and induced a dramatic morphological transition to convex lens-shaped particles. |
| 저자 |
양현승1, 구강희1, 신재만1, Kin Liao2, 김범준1
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| 소속 |
1KAIST, 2Khalifa Univ. |
| 키워드 |
emulsion; block copolymer particle; graphene; surfactant
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| E-Mail |
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