화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 봄 (04/27 ~ 04/29, 부산 BEXCO)
권호 22권 1호, p.713
발표분야 열역학
제목 Vapor-liquid equilibria data for methanol+ cyclopentyl methyl ether (CPME), cyclopentene + cyclopentyl methyl ether (CPME)
초록 Isothermal vapor-liquid equilibrium data for the binary system of methanol + cyclopentyl methyl ether(CPME) and cyclopentene+ cyclopentyl methyl ether(CPME) were measured at five equal-spaced temperatures between 313.15 and 353.15K using a circulation-type equilibrium apparatus. The experimental data were correlated with the Peng-Robinson equation of state using the Wong-Sandler mixing rule combined with the NRTL excess Gibbs free energy model. In addition, the average absolute deviations of pressure and vapor phase compositions between experimental and calculated values were reported, and the relevant parameters were determined. Calculated results with PR-EoS using both two mixing rules showed good agreement with experimental data with the average absolute deviation in percentage (AAD %) below 1.5 %.  
저자 정아영, 임종성
소속 서강대
키워드 열역학; 물성; 상태방정식; 상평형
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