| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2387 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Cycloaddition Reaction of Carbon Dioxide into Epoxides Using Tertiary Diamines |
| 초록 | To realize a true green CO2 utilization process, the development of a catalytic system having no toxic components is essential. In this report, we will present that tertiary amines without any metal or halide additives could be introduced as simple and green organocatalysts to activate CO2 and insert into epoxides, producing synthetically important cyclic carbonates. We will show simple diamine such as N,N,N’,N’-tetraethylethylenediamine could act as excellent catalyst for cycloaddition reaction. This new class of organocatalyst which does not have any toxic metals and halides is easy to handle and only requires as low as a 0.1 mol% loading. Additional favorable features include solvent free conditions and broad substrate scopes. Acknowledgment: 본 연구는 지역혁신창의인력양성사업(2014H1C1A1066874)의 지원을 받아 수행되었음 |
| 저자 | 김요셉1, 김혜진1, 김 민1, 김정곤2, 김영조1 |
| 소속 | 1충북대, 2전북대 |
| 키워드 | 기타 촉매분야 |
| 원문파일 | 초록 보기 |
