| 학회 |
한국화학공학회 |
| 학술대회 |
2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 |
22권 2호, p.2506 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Zirconium oxide based isoreticular MOF for the Chemical Fixation of CO2 with Epoxides |
| 초록 |
CO2 is a main greenhouse gas that leads to global warming. However it is a cheap, nontoxic, abundant and renewable C1 feedstock. Thus the chemical fixation of CO2 into useful products is of general interest from an environmental and economic point of view. The coupling reaction of epoxide with CO2 forming five membered cyclic carbonates is a highly atom economical way of fixing CO2. Five membered cyclic carbonates are employed as polar aprotic solvents, electrolyte solvents for lithium batteries, monomers for polymer synthesis, various chemical intermediates, degreasing agents etc. We studied the catalytic potential of zirconium oxide based MIL metal-organic framework (MIL-140 C) for the above transformation. Various physico-analytical techniques were used to characterize MOF. The MOF is active at room temperature and lower pressures of CO2 under co-catalyst free conditions. |
| 저자 |
김현준, 최각규, 김설희, 정혜민, Kuruppathparambil Roshith Roshan, 황규영, 박대원
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| 소속 |
부산대 |
| 키워드 |
촉매반응메커니즘 |
| E-Mail |
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| 원문파일 |
초록 보기 |
