화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 Synthesis and charaterization of indenofluorene-based white-emitting copolymers
초록 We report on the synthesis and characterization of a series of indeno[1,2-b]fluorene-based copolymers derived from 2,1,3-benzothiadiazole(BT), 4,7-bis(2-thienyl)-2,1,3-benzothiadiaz ole (DBT) and indeno[1,2-b]-fluorene (IF) by Suzuki Coupling reaction for applications in white PLEDs. The emitted color was successfully modulated by changing a feed ratio of three components, resulting incomplete fluorescence energy transfer. The thin films of the copolymers show white PL spectra via incomplete fluorescence resonance energy transfer from IF to BT and DBT. White-light electroluminescence from a single polymer has been obtained in a device with a configuration of ITO/PEDOT:PSS/polymer/Ca/Al. The device exhibits Commission Internationale de l’Eclairage (CIE) coordinates of (0.34, 0.35), a maximum brightness of 4088 cd/m2, a current efficiency 0.36 cd/A and relatively stable color coordinates at different driving voltages.
저자 정은재, 우한영
소속 부산대
키워드 white polymer light-emitting diode; incomplete fluorescence energy transfer
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