| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
정밀화학 |
| 제목 |
Synthesis and Characterization of New Paramagnetic Dinickel[(II)/(III)] Complexes ofthe Hexaaza Macrocyclic Ligands 1,8-Bis(2-Hydroxyethyl-2-Cyanoethyl)-1,3,6,8,10,13 -Hexaaza cyclotetradecane |
| 초록 |
The paramagnetic dinickel(II) complexes of formula [Ni(II)2(L)2(ox)]2 (2) have been prepared by the reaction of Ni(II) complexes of formula [Ni(II)L]2 with oxalate anion. The dinickel(III) complexes of formula [Ni(III)2(L)]2(ox)]4 (4) have been synthesized by the oxidation of the corresponding dinickel(II) complexes with nitric acid. The complexes are in the octahedral geometry for two Ni(II) ion, and tetragonally distorted octahedral geometry for two Ni(III) ion. |
| 저자 |
임운식, 김성권, 채규윤
|
| 소속 |
원광대 |
| 키워드 |
dinickel[(II)/(III)] complex; oxidation; epr; octahedral geometry
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| E-Mail |
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