화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 콜로이드·계면화학_포스터
제목 Effective Fabrication and Electrochemical Oxygen Evolution Reaction of Gold Multipod Nanoparticle Cores and NMOF-Derived Shell Nanohybrids
초록 In this report, a facile preparation of gold multipod nanoparticles (GMNs) embedded within cobalt sulfide nanocage is presented. The as-prepared GMN cores-ZIF-67 shell (GMN@ZIF-67) nanostructures can act as versatile sacrificial templates to the desired nanohybrids composed of multiple GMNs and cobalt sulfide (GMN@CoxSy) nanocages. Examination of electrocatalytic oxygen evolution reaction (OER) of the prepared nanocatalysts reveals that a type of GMN@CoxSy nanohybrid shows a substantially lower overpotential (η) value (345 mV) compared with those of GMNs (617 mV) and CoxSy nanomaterials (418 mV) at a current density of 10 mA cm−2. The enhanced OER is mainly attributed to the highly effective core−shell interfaces originating from the unique multibranch topologies of the GMN cores as well as the optimized cobalt sulfide shells of the nanohybrids.
저자 MAIDUYHIEN, 유효종
소속 한림대
키워드 Gold multipod nanoparticle; cobalt sulfide; nanohybrid; oxygen evolution reaction
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