학회 | 한국고분자학회 |
학술대회 | 2002년 봄 (04/12 ~ 04/13, 서울대학교) |
권호 | 27권 1호, p.195 |
발표분야 | 특별 심포지엄 |
제목 | Synthesis and properties of block copolymers containing 2-(dimethylamino)ethyl methacrylate and fluoro octyl methacrylate by GTP |
초록 | Living polymerization techniques such as anionic and group transfer polymerization (GTP) allow a preparation of well-defined block copolymer by sequential addition of different monomers. In our previous work, block copolymers containing poly methacrylic acid (PMAA) and poly 1,1,2,2-perfluoro octyl methacrylate(FOMA) were synthesized by GTP and they were found to be effective for anionic surfactant in CO2. In this study, we prepared poly(2-(dimethylamino)ethyl methacrylate)-b-poly(1,1,2,2-fluoro octyl methacrylate) by GTP with controlled molecular weight. The amphiphilic copolymer formed micelles in chloroform, which was observed by DLS and TEM. The copolymers were also effective in carbon dioxide application. |
저자 | 임권택, 황하수, 이수현 |
소속 | 화상정보공학부 |
키워드 | |