화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자구조 및 물성
제목 Thin Film Deposition of Porphyrin Based Metal-Organic-Frameworks(MOFs) on Functionalized Self-Assembled-Monolayers(SAMs) on Gold Chip
초록 Metal Organic Frameworks(MOFs) are highly ordered materials prepared by self-assembly of metal ions and organic linkers. Many researchers focused on MOFs thin film because highly porous thin layer can be used as sensors and catalysts. Specifically, porphyrin based MOFs thin film is interesting because of cavity in porphyrin structure which metal ions can coordinate. However, MOFs are not soluble in common solvents, so it is hard to change to other form suc as thin film. For resolving this problem, we tried to make thin layer of MOFs, which contain porphyrin structure, on -COOH and -NH2 terminated Self-Assembled-Monolayers(SAMs) on Au through solvothermal reaction. Here, we report deposition thin film using IRMOF-1, PPF-1-Zn/Zn, and MOF 525. Specifically, MOF-525 has high stabilit so it can be used for sustainable sensor.
저자 권정욱, 강규민, 최은영
소속 카이스트 부설 한국과학영재학교
키워드 MOFs; Thin film; Porphyrin; Sensor
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